@KimmoPaukku: I pressed the red SW button for 0.5 seconds up to 10 seconds. no difference. @vk_1: I also unplugged already the whole battery - the LEDs were not showing up.
From the instruction which is in the set, I read that all dip-switches need to be up in both batteries. the master will be assign according the linkport1 and linport0.
What seems to be weired is, that the Multiplus actually now acts as a BMS and is also able load the battery and read the SOC: