Some further thoughts as the installation of the Multiplus has started this.
- Is everything wired correctly to the shunt, do either of the MPPT or Multiplus negatives connect directly to the battery. See linked FAQ.
- Are you reading SOC though something like a GX device (Cerbo e tc), if so is the SmartShunt set as the battery monitor or the Multiplus. On the GX check Settings / System Setup / Batteries / Battery Monitor.
As noted previously, to help diagnose this, please post a screenshot of the SmartShunt trend for battery current and battery voltage as the MPPT goes to float. This should cover the last 30 minutes in absorption through to 5 minutes or so after float. Also your current SmartShunt settings.