I have an Orion XS 1400 and a pair of SmartSolar 100/50 chargers in my RV, charging a bank of SOK 24v batteries with CAN communication. DVCC is configured to control everything.
Have you activated the limit charge feature though?
Excerpt from your link..
Limit charge current is a user-configurable maximum charge current setting. It works across the whole system, whereby Solar is prioritised first, then the Orion XS DC-DC battery charger and then the inverter/charger.