I know that I have said this before, but the new information really does help understand and I believe that this may be the issue.
The alternators charge the house batteries, hence the house batteries charge the engine batteries because the alternator output is connected to the house batteries. The only way that this could be stopped is if you have the alternator output going to a switching device such as an ArgoFET and the Orions are connected to one output and the lithium house bank to another. I find this hard to believe, so I am going to write this on the basis that the Orions are essentially connected to the house bank.
Clearly in this image I am going to assume that the engine is not running but the one Orion shown is in bulk charge and your batteries are starting to float. So the boat builders assertion that the Orions could not draw from the house batteries is wrong in my view, because the screenshot clearly shows otherwise.
The Orions are set up with voltage lockout and engine shutdown detection

Voltage lockout means that charging will not start until the house batteries are above 13.5V and when they fall below 13.4V they stop charging, these settings over ride the engine lock out.
The engine shutdown detection means that once 13.5V has been charging can start. If the voltage is above 14.0V it starts immediately, otherwise it starts after 120 seconds. These voltages are reached by solar charging so the Orions will charge the engine batteries from solar, which is not a bad thing if you are going on longer periods without running the engines as it keeps up with the parasitic loads on the engine batteries. The Orion settings are safe because they will stop the engine batteries discharging the lithium batteries as stopping at 13.4V will be around 90-95% SOC.
What is probably happening with your system is that the Orions start to charge the engine batteries just as the lithium batteries are almost full, the voltage ramps up very rapidly towards the end and the batteries as full because it is a low charge rate compared to the battery capacity.
Prior to charging you have a current load of around 20A, solar generates 60A so you charge at 40A. At the end of solar charging, the Orions start to charge and lets assume that they take 30A each, consume all that the the solar is producing, so you then go back to the case that once these start charging, your consumption exceeds the production so your batteries start discharging. As the batteries start discharging before the SmartShunt has synchronised it never will. I was convinced early on that you had a load kicking in at this time and we went around the load output, here it is.
Things to think about.
In terms of your shunt and synchronisation, it may be best to reduce the charged voltage to 13.7V or 13.8V and a tail current of 4% and a charged detection time of only 1 minute so that it synchronises much sooner and works with your set up and gets a reset to 100% to avoid long term drift. The risk is an occasional reset to 100% too early.
Changes could be made to the Orions to stop them charging as much or changing from engine shutdown detection to switched from the ignition wire so they definitely only come on with the engine(s). Using the solar to keep the engine batteries topped up is usually a good thing.
You will need to look at your data to see if they worked better with the VE Smart Network or not, was synchronised operation better.
Do a trial, turn the Orions off in victronConnect battery settings page for a day and see what happens.