Yes you can use these transformers in this manner, but I would also include an RCCD device on the output for further protection.( assuming the equipment under repair does not have too great an earth leakage current).
Transformers are pretty good at inrush currents, due to high thermal mass.
@GUMPY Reason for using this would be to help protect personnel diagnosing / repairing live powered equipment.
These days if needed I use a small inverter to power the equipment under test, thus keeping the ac fully isolated. This is ok for single fault condition - i.e. one hand /finger touching a live circuit. Also helps if using an oscilloscope for probing live / non isolated supplies.