You are allowed to disagree with me of course, but, then you also have to come with facts. I might tell you things you were not aware of yet and don’t fit in your world yet, but that does not mean they are not true. First of all, your advice to me to do more study. Well, I studied LiFePO4 for a long long time and read most scientific research which has been done on this topic. Did you?
Now, lets look at the facts
“To clarify : I’m talking about the mass-market consumer LFP batteries which are largely coming from China, and are probably over 90% of LFP batteries on the market these days for DIY.
That’s the most common battery a Victron device is going to be connected to, and it would make sense for Victron to offer a profile which works with these batteries”
That’s a fact, however, has nothing to do with the usage of those cells. They are being used for marine grade batteries (like my company builds them) and ESS systems. So, you are not saying anything of any value here. Using them in maritime installations have other requirements then ESS.
”This is not true - modern LFP cells have thousands of cycles even at 100% DOD and when stored at 100% SOC. Most people are more at risk of calendar aging (e.g. time) rather than cycles or storage SOC.
Perhaps you are thinking of older chemistries such as NMC?”
No, I’m not. I’m talking about LFP. Why do you think Tesla and Apple are recommending 80% instead of fully charged every time? But, okay, let’s go to the real knowhow. This report is of your interest. They tested several stages of SCO for LFP for a longer time and the research shows that the higher the SOC for storage, the more degradation. Just read the report. There are more studies on this if you want to.
Study of aging mechanisms in LiFePO4 batteries with various SOC levels using the zero-sum pulse method - ScienceDirect
Dahn et all: The Operation Window of Lithium Iron Phosphate/Graphite Cells Affects their Lifetime - IOPscience
And this one is a good read too: Systematic aging of commercial LiFePO4|Graphite cylindrical cells including a theory explaining rise of capacity during aging - ScienceDirect
Last but not least: Erik of Nordkyn Design has done thorough study on this subject too. If you did not read it yet, you should. This is ‘the bible’ : Lithium battery systems | Nordkyn Design
“This isn’t good advice - many consumer LFP batteries require 14.1V for the top-end balancing process to even begin. If you charge below this, you deny the BMS the chance to do cell balancing. If you aren’t familiar with these batteries, I encourage you to do some research: look up some of the common names (WattCycle, SOK, EcoWorthy, LiTime…) Many of these have very similar specifications, and in many cases, they are literally the same battery being re-branded.”
This is really awkward. I’m sorry, but LiTime, WattCycle are not the grade A suppliers. They don’t use EVE cells or Winston. Furthermore, it depends on the BMS when cells get balanced. A good BMS can balance on every voltage you specify. It makes perfect sense to start balancing on let’s say 3.4V/cell. If you absorb at 3.45V then GOOD cells have enough time to balance. There is no need to go any further, it only stresses the cell. Again, the proof: Panda did testing: https://panbo.com/charging-lifepo4-whats-the-impact-of-lower-voltages/ and also, a channel you might be familiar with, Off the Grid Garage, did several tests on this.
Also we did several tests on this. In fact, if you set a good tailcurrent with charging and use a good CC/CV Profile, you might get even more energy out of the cell with ‘just’ charging it to 3.45.
Sample 1 shows an EVE LF304 cell charged to the common 3.65V: 307,80Ah and 994.49Wh.
Sample 2 shows the same cell, but now charged to 3.45V and with a tailcurrent at 1A. Total discharged 308.60Ah and 997.54Wh:
We also did testing what happened if the cell was charged with 3.45 with a good absorption profile. There are diagrams of it too. But in short; no energy was stored in the cell anymore, temperature and pressure were rising and with a loadcell to measure the pressure in the cell we saw that the pressure was disproportionately high when charging from 3.45 to 3.65. Doesn’t proof anything, but it’s a good sign lithium plating is taking place at that moment.
I’ll leave you with that. Very eager to learn from you which research shows that storage at 100% SOC does not make any difference.